You cannot build or use your own custom theme built from scratch at WordPress.com.
The only themes we can use are those found here > Appearance > Themes
This is a multiuser blogging platform. All blogs wearing the same theme are using the same underlying template and we cannot access the underlying files and edit templates or themes. http://en.support.wordpress.com/themes/editing-themes/
There are two free themes, Sandbox and Toolbox designed to allow maximum flexibility for CSS editing and creating new “skins”. Toolbox is more modern and includes a lot of support for CSS3 and HTML5, so it is really only limited by your skills and knowledge.
If you have CSS editing experience the upgrade will allow you to stylize the appearance of themes you find here > Appearance > Themes, but will not allow you to change the functionality, by editing the underlying template. It does not allow you to remove footer links to the theme designer or to WordPress.com. Also note that CSS is theme specific, so you cannot use the CSS stylesheets from other themes with the themes at WordPress.COM. http://en.support.wordpress.com/custom-design/custom-css/
See also > WordPress.com vs. WordPress.org: The Differences > http://support.wordpress.com/com-vs-org/
If you are expecting to be able to click a button and change fonts throughout your blog then it’s not that easily done.
These are 3 ways to change fonts on wordpress.com blogs.
(1) Changing font families, colors and size in text in posts or pages either post by post or page by page by coding into the HTML editor. http://en.support.wordpress.com/editors/font-size-color/
(2) Changing font colors in text in posts or pages either post by post or page by page using the #4 icon (Select text color – change the text color) in Row 2 the Visual editor. http://en.support.wordpress.com/visual-editor/#row-2
(3) Changing all font families, colors and sizes throughout the whole blog by purchasing an annually renewable Custom Design upgrade and using Typekit Fonts with Staff support. http://en.support.wordpress.com/custom-design/
Note: A few themes do provide for changing font color in the Blog Title and/or optional Tagline and/or links. In the majority of themes font changes to font families, colors and size in the blog title, tagline, menu, post titles, page titles, categories and tags, widget headings, comments, and links cannot be done without CSS editing.