Unfortunately, new posts, especially on new blogs, only rarely show up immediately on Google.
Google and other search engines will eventually index your blog and your posts will show up in search results. However, exactly when search engines get to your site and how they choose to rank your posts is not something that we can control.
See the Search Engines page for more information about how search engines work with WordPress.com. You may also want to check out the Webmaster Tools page, for help with getting more data from Google and other search engines about how they index your blog.
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